六氟化硫(SF6)示踪剂及其在大气扩散中的应用
SULFUR HEXAFLUORIDE TRACER AND ITS APPLICATION TO ATMOSPHERIC DIFFUSION
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摘要: 六氟化硫(SF6)示踪剂是新发展的一种有效气体扩散示踪物。本文是国内SF6示踪法应用于大气扩散实验研究的初次尝试的一些结果。1976年夏,我们初步建立了大气中SF6示踪样品的气相色谱分析法,检测灵敏度达2×10-11(与空气体积比,以下同),最佳达5×10-12,接近国际同类方法的检测水平。1976年秋,在沿海岸某地进行了六次扩散实验,检测了七公里范围内SF6示踪样品,获得了沿横截风向浓度分布较清晰的廓线,其形状一部分近似正态分布。1977年冬,用同样方法在北京西部山谷作了十次扩散实验,检测了谷内水平和空中垂直浓度分布,初步测定的σy和σz扩散系数比平坦开阔地区要偏大几倍。Abstract: In the paper an experimental study of atmospheric diffusion using SF6 as tracer is described. The gas chromatagraphic analysis has a sensitivity of 2×10-11, with an optimun value 5×10-12 (parts SFis per part of air). The experiments were carried out in 1976-1977 for different kinds of topography along coastal Tracer samples were taken downwind to 7 km. A distinct concentration profile of nearly normal distribution has been obtained in the crosswind direction.